Shanghai Kingzhi New Materials Technology Co., Ltd. · Shanghai and Hong Kong
Blue and red labelled steel drums of chain extender raw material

1,4-Butanediol BDO Chain Extender

High purity BDO at 99.8 percent with matched amine catalysts

Overview

What This Product Is and Who Buys It

1,4-Butanediol is a high purity low moisture diol and the standard chain extender for polyurethane systems. It is a colourless transparent liquid that turns to a white waxy solid at low temperature, and it is supplied at 99.8 percent purity with water held at 0.05 percent maximum.

Key Benefits

  • Purity of 99.8 percent minimum with colour at 10 APHA maximum
  • Water content at 0.05 percent maximum, because moisture in the extender becomes bubbles in the part
  • Excellent reactivity and storage stability
  • Supplied alongside matched amine catalysts and auxiliaries in the same order
Blue and red labelled steel drums of chain extender raw material
Blue and red labelled steel drums of chain extender raw material
Bulk tanks IBC totes and drums at a chemical storage terminal
Bulk tanks IBC totes and drums at a chemical storage terminal
Applications

Where This Material Is Used

Polyurethane elastomers and TPUPolyester polyolsPBT engineering plasticsGamma butyrolactone and NMP productionPharmaceutical intermediates and electroplating brightenersCOPES thermoplastic elastomers

Who It Is For

  • Cast polyurethane elastomer producers
  • TPU and PBT manufacturers
  • Polyester polyol producers
  • Water based coating formulators needing pH adjusters and catalysts

Problems It Solves

  • Bubbles and soft spots in cast elastomer parts traced back to water in the chain extender
  • Colour in the finished part traced back to colour in the extender
  • Water based systems needing a pH adjuster and a polyurethane catalyst from the same supplier
Technical

Technical Features

  • Colourless transparent liquid, white waxy solid at low temperature
  • Solid point 20°C, boiling point 228 to 230°C, flash point 134°C
  • Viscosity 90 cP at 20°C and 25 cP at 50°C
  • Supplied in 200 kg drums

Specifications

These figures are the manufacturer grade data as published for this product family. Anything not listed below has not been confirmed and is marked TBC on request rather than estimated.

Product NameCAS No.PurityApplication
N,N-Dimethylethanolamine (DMEA)108-01-099.8%Raw material for polyamide-polyurea resins; pH adjuster for water-based coatings; polyurethane catalyst
N,N-Dimethyl-1,3-propanediamine (DMAPA)109-55-799%Intermediate for betaines, ion-exchange resins, liquid paper dyes, pharmaceuticals and electroplating
ItemStandard
AppearanceColourless transparent liquid, white waxy solid at low temperature
Purity (Wt%)≥99.8
Color (APHA)≤10
Water (Wt%)≤0.05
Specific Gravity (25/4℃)1.012–1.016
Solid Point20℃
Boiling Point228–230℃
Flash Point134℃
Viscosity90 cP (20℃) / 25 cP (50℃)

Grades listed are representative and not exhaustive. Ask for the batch certificate of analysis on the grade you intend to buy.

Handling

Packaging Storage and Shelf Life

Packaging
200 kg per drum
Solid Point
20°C, so the product solidifies in cool storage and needs warming before use
Storage
Sealed containers; the water specification of 0.05 percent maximum only holds if moisture is kept out
Flash Point
134°C
Use Guide

How to Work With This Product

  1. Warm the drum above the 20 degree C solid point before decanting in cold weather
  2. Check water content on the certificate before a cast elastomer run
  3. Reseal immediately after decanting, since BDO is hygroscopic
  4. For water based coating work, order the matched DMEA pH adjuster and catalyst at the same time
Comparison

How It Compares

Within the Solvent and Chain Extenders category this product is positioned by the numbers in the table above rather than by a marketing claim. Compare NCO content, viscosity, equivalent weight or hydroxyl value against the alternative you are considering, and if the two are close, ask us for both samples and decide on your own line.

Quality and Documentation

Quality control runs across incoming raw materials, production and finished product inspection. A batch certificate of analysis is supplied with every shipment. We are a supply and trading company working with named manufacturers and OEM partners, so certification held by the producing plant is provided on request per grade rather than claimed here as ours.

Customisation

Customised grades and packing formats are available through our OEM partners and specialised manufacturing facilities. Tell us the property you need to move and we will say whether it is a grade change, a packaging change or not possible.

FAQ

1,4-Butanediol Questions

Why does purity matter so much for a chain extender?

Because the chain extender is a small part of the formulation with a large effect on the hard segment. At 99.8 percent purity and 0.05 percent maximum water, the variables that cause bubbles and soft spots are controlled.

What happens if the drum solidifies?

That is normal below 20 degrees C, the stated solid point. Warm the drum to redissolve; the material is a white waxy solid at low temperature by design.

What catalysts do you supply alongside BDO?

N,N-Dimethylethanolamine, CAS 108-01-0 at 99.8 percent purity, used as a pH adjuster for water based coatings and a polyurethane catalyst; and N,N-Dimethyl-1,3-propanediamine, CAS 109-55-7 at 99 percent purity, used as an intermediate for betaines, ion exchange resins and pharmaceuticals.

What packaging is standard?

200 kg per drum.

Request a Quote or a Sample of 1,4-Butanediol

Samples take about 7 days and are free of charge with shipping at your cost. Production orders ship 20-30 days after the deposit is received.